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Monitoring of environmental exposure to polycyclic aromatic hydrocarbons: a review

You have full access to this open access article. Polycyclic aromatic hydrocarbons PAHs are a large group of organic compounds with two or more fused aromatic rings. They have a relatively low solubility in water, but are highly lipophilic.

Most of the PAHs with low vapour pressure in the air are adsorbed on particles. When dissolved in water or adsorbed on particulate matter, PAHs can undergo photodecomposition when exposed to ultraviolet light from solar radiation.

In the atmosphere, PAHs can react with pollutants such as ozone, nitrogen oxides and sulfur dioxide, yielding diones, nitro- and dinitro-PAHs, and sulfonic acids, respectively. PAHs may also be degraded by some microorganisms in the soil. PAHs are widespread environmental contaminants resulting from incomplete combustion of organic materials. The occurrence is largely a result of anthropogenic emissions such as fossil fuel-burning, motor vehicle, waste incinerator, oil refining, coke and asphalt production, and aluminum production, etc.

PAHs have received increased attention in recent years in air pollution studies because some of these compounds are highly carcinogenic or mutagenic. Eight PAHs Car-PAHs typically considered as possible carcinogens are: benzo a anthracene, chrysene, benzo b fluoranthene, benzo k fluoranthene, benzo a pyrene B a P , dibenzo a,h anthracene, indeno 1,2,3-cd pyrene and benzo g,h,i perylene.

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